Zogulitsa

Zovuta [Cp*Ru(MeCN)3]PF6 zikuwonetsedwa kuti zithandizire hydrosilylation ya ma alkynes osiyanasiyana.Terminal alkynes amakwanitsa kupeza zinthu za alpha-vinylsilane zokhala ndi regioselectivity yabwino.Kafukufuku wamalebulo a Deuterium akuwonetsa kuti njira yowonjezeretsa yoyera ikugwira ntchito.Zovuta zomwezo zimagwira ntchito mkati mwa alkyne hydrosilylation, kumene kusankha mtheradi kwa njira yowonjezera yowonjezera kumasungidwa.Magulu angapo amkati a alkyne gawo lapansi, kuphatikiza ma alcohols a propargylic ndi alpha, beta-alkynyl carbonyl mankhwala, amalola kupanga regioselective vinylsilane.Kulekerera kwamitundu yosiyanasiyana ya silanes ndikodziwika, kuphatikiza alkyl-, aryl-, alkoxy-, ndi halosilanes.Ubwinowu ukuwonetsedwa mu kaphatikizidwe kachindunji ka magawo atatu a silicon-tethered intramolecular Diels-Alder cycloadditions.