Zogulitsa

Glucaminium-based ionic liquids ndi gulu latsopano la zakumwa za ayoni zomwe zapangidwa posachedwapa ndipo zokonzedwa ndikugwira ntchito ndi gulu la amine la N-methyl-d-glucamine, zomwe zimawapangitsa kukhala abwino a hydrophilicity chifukwa cha kupezeka kwa shuga ndi gulu la quaternary ammonium.Pakafukufuku wapano, glucaminium-based ionic liquid N,N-diallyl-N-methyl-d-glucaminium bromide idapangidwa ndipo kenako imamangirizidwa pamwamba pa 3-mercaptopropyl zida zosinthidwa za silica kudzera mu "thiol-ene" dinani chemistry.Gawo loyima lomwe linapezedwa limadziwika ndi kusanthula kwazinthu komanso ma infrared spectroscopy, kenako ndikudzaza ngati gawo la HPLC.Chisakanizo cha ma nucleosides asanu chinagwiritsidwa ntchito kuwonetsa kulekanitsa kwa gawo lomwe lapezeka pansi pa HILIC mode ndipo magwiridwe antchito adatsimikiziridwa ndi cytidine monga kuyesa solute, kufikira 80,000plates / m.Kenako, machitidwe osungira adawunikidwa pofufuza momwe zinthu zosiyanasiyana za chromatographic zimakhalira posungira mitundu yosiyanasiyana ya solutes, ndipo zotsatira zake zidawonetsa kuti gawo lopangidwa ndi glucaminium-based ionic fluid stationary gawo likuwonetsa kuyanjana kwa hydrophilic / anion-exchange-exchange- njira yosungiramo mode.Pomaliza, zosakaniza ziwiri za nucleotides ndi flavonoids zidalekanitsidwa pazambiri zamadzimadzi a glucaminium, motsatana pansi pa kuyanjana kwa hydrophilic ndi hydrophilic interaction/anion-exchange mix-mode chromatography.Pomaliza, kuthekera kosunga ma multimodal a glucaminium-based ionic fluid fluid atha kupereka njira zambiri zosungira komanso kusankha kosinthika kuzinthu za polar ndi hydrophilic.